Syntheses and Structures of Transition Metal Complexes of Quinoline-Containing Multidentate Amine Ligands

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aut.relation.articlenumber215599
aut.relation.endpage215599
aut.relation.journalCoordination Chemistry Reviews
aut.relation.startpage215599
aut.relation.volume502
dc.contributor.authorCarr, B
dc.contributor.authorFleming, CL
dc.contributor.authorBlackman, AG
dc.date.accessioned2024-01-09T23:40:12Z
dc.date.available2024-01-09T23:40:12Z
dc.date.issued2024-03-01
dc.description.abstractThe literature pertaining to tri-, tetra-, penta-, and hexadentate amine ligands containing unsubstituted quinoline moieties is reviewed. The syntheses of these 46 ligands are detailed, and all X-ray structurally characterised transition metal complexes of these ligands are compiled and discussed. Comparisons to the analogous pyridine complexes, where they exist, are made. Most differences are found amongst the five-coordinate complexes, where the quinoline complexes mostly exhibit square pyramidal geometries, while the analogous pyridine complexes are predominantly trigonal bipyramidal. A structural feature we term the quinolyl split, where one or two quinolyl rings bisect an X-M-X angle, in contrast to their pyridine congeners, is identified.
dc.identifier.citationCoordination Chemistry Reviews, ISSN: 0010-8545 (Print), Elsevier BV, 502, 215599-215599. doi: 10.1016/j.ccr.2023.215599
dc.identifier.doi10.1016/j.ccr.2023.215599
dc.identifier.issn0010-8545
dc.identifier.urihttp://hdl.handle.net/10292/17074
dc.languageen
dc.publisherElsevier BV
dc.relation.urihttps://www.sciencedirect.com/science/article/pii/S001085452300588X
dc.rights© 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
dc.rights.accessrightsOpenAccess
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject3402 Inorganic Chemistry
dc.subject34 Chemical Sciences
dc.subject0302 Inorganic Chemistry
dc.subject0306 Physical Chemistry (incl. Structural)
dc.subject0399 Other Chemical Sciences
dc.subjectGeneral Chemistry
dc.subject3402 Inorganic chemistry
dc.subject4003 Biomedical engineering
dc.titleSyntheses and Structures of Transition Metal Complexes of Quinoline-Containing Multidentate Amine Ligands
dc.typeJournal Article
pubs.elements-id534233
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