Syntheses and Structures of Transition Metal Complexes of Quinoline-Containing Multidentate Amine Ligands
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Carr, B
Fleming, CL
Blackman, AG
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Elsevier BV
Abstract
The literature pertaining to tri-, tetra-, penta-, and hexadentate amine ligands containing unsubstituted quinoline moieties is reviewed. The syntheses of these 46 ligands are detailed, and all X-ray structurally characterised transition metal complexes of these ligands are compiled and discussed. Comparisons to the analogous pyridine complexes, where they exist, are made. Most differences are found amongst the five-coordinate complexes, where the quinoline complexes mostly exhibit square pyramidal geometries, while the analogous pyridine complexes are predominantly trigonal bipyramidal. A structural feature we term the quinolyl split, where one or two quinolyl rings bisect an X-M-X angle, in contrast to their pyridine congeners, is identified.
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3402 Inorganic Chemistry, 34 Chemical Sciences, 0302 Inorganic Chemistry, 0306 Physical Chemistry (incl. Structural), 0399 Other Chemical Sciences, General Chemistry, 3402 Inorganic chemistry, 4003 Biomedical engineering
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Coordination Chemistry Reviews, ISSN: 0010-8545 (Print), Elsevier BV, 502, 215599-215599. doi: 10.1016/j.ccr.2023.215599
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© 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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Except where otherwise noted, this item's license is described as © 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).