Electric vehicles (EVs) are regarded as essential solutions for alleviating climate change and energy crises. EVs can store excess Photovoltaic (PV) generation and transfer energy to other EVs, reducing distribution network upgrade costs. However, the limited range of EVs coupled with inadequate charging infrastructure leads to range anxiety among EV users, thereby becoming a barrier to implementing a transactive energy management system. This research quantifies the range anxiety among EV users and proposes a novel trading mechanism for transactive trading between workplace EVs. The case study solved for a commercial region in Auckland shows a 3–10% reduction in charging cost compared to a conventional V2G system. Further analysis shows that public charging stations can also result in cost savings from 1% to 5%. Still, their impact is limited compared to the number of discharging EVs participating in transactive trading. The uncertainty analysis of PV generation under different scenarios also shows the cost savings of the proposed strategy. The simulation results verify the feasibility and effectiveness of the proposed strategy while alleviating range anxiety among EV users.