Characterisation of volatile compounds from the leaves of six Pittosporum species; an instrumental and sensory evaluation

aut.embargoNoen_NZ
aut.thirdpc.containsNoen_NZ
aut.thirdpc.permissionNoen_NZ
aut.thirdpc.removedNoen_NZ
dc.contributor.advisorWhiting, Roger
dc.contributor.advisorRobertson, John
dc.contributor.authorYu, Shanshi
dc.date.accessioned2013-08-21T04:15:17Z
dc.date.available2013-08-21T04:15:17Z
dc.date.copyright2013
dc.date.created2013
dc.date.issued2013
dc.date.updated2013-08-21T00:50:52Z
dc.description.abstractSix Pittosporum species native to New Zealand, P. cornifolium, P. crassifolium, P. eugenioides, P. kirkii, P. tenuifolium, and P. umbellatum, were investigated in this study. The 88 volatile compounds released from their leaves were identified by head space SPME whose optimized conditions are fibre coating PDMS, extraction time 30mins and extraction temperature 70°C with GC-MS analysis. Most of these volatile compounds were identified as sesquiterpenes, 21 of which were shown to be major constitutes in the Pittosporum species. They are α-pinene, sabinene, β-pinene, β-myrcene, limonene, α-copaene, (-)-β-bourbonene, β-cubebene, α-gurjunene, β- caryophyllene, cis-thujopsene, humulene, alloaromadendrene, γ-muurolene, germacrene D, β-cadinene, bicyclo[3.1.1]hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)-, naphthalene, 1,2,4a,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S-endo)-, 4,4-dimethyl-3-(3-methylbut-3-enylidene)-2-methylenebicyclo[4.1.0]heptane and cyclohexane, 1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-. The main components in P. cornifolium, P. crassifolium, P. eugenioides, P. kirkii, P. tenuifolium, and P. umbellatum are germacrene D, α-copaene, nonane, germacrene D, β-caryophyllene and cyclohexane, 1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-, respectively. The GCMS fingerprint spectra clearly showed the difference of these plants. Six of the Pittosporum species were also subjected to projective mapping of their odour profiles. This showed “green” and “sweet” as general descriptors for all the Pittosproum. However, P. kirkii and P. cornifolium were also described as “fruity” and “floral”. The aromas of P. umbellatum, P.tenuifolium and P. crassifolium as “bitter”, “woody” and “grassy” with a sense of “spicy” and P. eugenioides as having a “citrus” odour.en_NZ
dc.identifier.urihttps://hdl.handle.net/10292/5611
dc.language.isoenen_NZ
dc.publisherAuckland University of Technology
dc.rights.accessrightsOpenAccess
dc.subjectSPMEen_NZ
dc.subjectPittosporumen_NZ
dc.subjectSensoryen_NZ
dc.subjectPCAen_NZ
dc.titleCharacterisation of volatile compounds from the leaves of six Pittosporum species; an instrumental and sensory evaluationen_NZ
dc.typeThesis
thesis.degree.discipline
thesis.degree.grantorAuckland University of Technology
thesis.degree.levelMasters Theses
thesis.degree.nameMaster of Applied Scienceen_NZ
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